Defendants' Answer to CID at 1(g) and 5(c) (the defendants have no competitors; the City does not consider anyone as a competitor) (Exhibit 2); Langley Dep. The symbol Eocell represents the standard electrode potential of a cell. and you must attribute OpenStax. (2023, April 5). at 56-58 (Exhibit 4); Defendant's Answer to CID at 5(c) ("There is no one else to provide water and sewer service, which is not a lucrative venture") (Exhibit 2). What mass of copper is produced? Answer of Defendants at 2 (Exhibit 1); Defendants' Answer to CID at 1 (Exhibit 2); Adair Dep. Thus, customers in Adair County do not have a choice of water suppliers. then you must include on every physical page the following attribution: If you are redistributing all or part of this book in a digital format, c) The electrode potential of the standard hydrogen electrode is exactly zero. at 42-43 (Exhibit 6). 39. Adair Dep. 0.048 mol 2.9 mol 0.15 mol 6.9 mol 0.073 mol 4. The meaning of STANDARD-ISSUE is standard, typical. B) Electrons will flow from more negative electrode to more positive electrode. If the inputs were swapped, the reported voltage would be +0.47 V. The entry for the putative oxidant, Fe2+, appears above the entry for the reductant, Cr, and so a spontaneous reaction is predicted per the quick approach described above. OF JUSTICE INVESTIGATION BEGAN. 31. Adair Dep. Rucker Dep. 35. The spontaneous reaction that occurs in this cell is not a redox reaction. 9th ed. This book uses the A negative EO value means that the substance will undergo spontaneous oxidation reaction with respect to SHE. If Ozarks had been allowed to compete and serve more customers in the annexed areas of Stilwell, it could have bought more equipment (i.e. Potentials are measured in the volt unit, defined as one joule of energy per one coulomb of charge, V = J/C. 45. Ozarks had offered to provide electric service to Candle Ridge. Except where otherwise noted, textbooks on this site The above projects generate roughly the following annual electricity revenues: Skywood ($32,000); Skywood I ($35,000); Henningsen's Cold Storage ($100,000); Wilma P. Man Killer Health Clinic ($20,000); Two J. The standard reduction cell potential and the standard oxidation cell potential can never be combined. at 40 (Exhibit 6); Letter from Crozier to Rucker dated August 11, 1993 (Exhibit 16). c Cu2+ can oxidize Cd, and Cd can reduce Al3+. at 80-81 (Exhibit 6). Reconsideration of the two redox reactions in Example 17.4 provides support for this fact. Defendants' Answer to CID at 1(g) and 5(c) (the defendants have no competitors; the City does not consider anyone as a competitor) (Exhibit 2); Langley Dep. The standard cell potential is the potential difference between the cathode and anode. at 15-16, 41-42, 53-54, 94-95, 118-120 (Exhibit 3); Langley at 19, 63-64 (pre-condemnation, Ozarks had 125 customers in annexed territory) (Exhibit 4); Answer of Defendants at 11 (Exhibit 1). It is also a member of the Southwest Power Pool, a coordinated electric power interchange system headquartered in Arkansas that consists of multiple members from eight states throughout the Southwest. D) Ecell is the difference in voltage between the anode and the cathode. When you visit the site, Dotdash Meredith and its partners may store or retrieve information on your browser, mostly in the form of cookies. 640, 655 (1997). at 86 (Exhibit 3); Rucker Dep. When solving for the standard cell potential, the species oxidized and the species reduced must be identified. The cell potential, E c e l l, is the measure of the potential difference between two half cells in an electrochemical cell. Letter from Cole to Read dated October 21, 1997 (Exhibit 10); Crozier Dep. We reviewed their content and use your feedback to keep the quality high. at 36-37 (Exhibit 4). 44. Our mission is to improve educational access and learning for everyone. Which one of the following statements about the half-cell processes is true for the cell, Cd | Cd2+ (1 M)||Cu 2+ (1 M)| Cu? It is also important to note that this potential can vary with a change in pressure, temperature, or concentration. The standard state also includes several additional restrictions. Ozarks intends to continue to compete and solicit new customers in the annexed areas. Explain how standard reduction potentials or standard oxidation potentials are applied. As the media continues to evaluate the significance of the Common Core and data from Common Core states begin to pour in, you can bet the debate will rage on. Adair at Dep. Crozier Dep. https://www.thoughtco.com/difference-between-standard-conditions-state-607534 (accessed August 22, 2023). Have a question about Government Services? This platinum electrode is dipped in 1M solution of H + ions ( mostly in HCl ). Both STP and standard state specify a gas pressure of 1 atmosphere. at 71-72 (Exhibit 6). Defendants' Answer to CID at 5(a) (Exhibit 2); Adair Dep. at 52-53 (Exhibit 4). A cell potential of +0.337 V is measured, and so. Standard Electrode Potentials - HyperPhysics The electrode potential (EX) for a half-cell X is defined as the potential measured for a cell comprised of X acting as cathode and the SHE acting as anode: When the half-cell X is under standard-state conditions, its potential is the standard electrode potential, EX. 34. 25. Step 3/5 3. B) The electrode potential of the standard hydrogen electrode is 32. Helmenstine, Anne Marie, Ph.D. "Standard Conditions Versus Standard State." Adair Dep. The Cell Potential - Chemistry LibreTexts Petrucci, Harwood, Herring, and Madura. Download the mobile app and receive 3 free video solutions, Access past notes and exams matches to your classes, Study with your friends by joining virtual study sessions, Educator app for at 26-28, 41 (Exhibit 13); Crozier Dep. A strip of metal in a solution of ions of that metal is an electrode potential. Defendants directly purchased more than $680,000 worth of goods and services between 1995 and the first quarter of 1997 from out-of-state companies. Zhumdal, Zhumdal. BCHEM 163 Exam 4 Flashcards | Quizlet at 51-52 (Exhibit 3). Considering the nature of potential in this context, it is clear that the potential of a single half-cell or a single electrode cant be measured; transfer of electrons requires both a donor and recipient, in this case a reductant and an oxidant, respectively. 10. a. E^o cell is positive for spontaneous reactions b. Examples can be seen in Cell Potentials. Measured against standard hydroden electrode. Post any question and get expert help quickly. PROS: Standardized tests allow for students to be compared to others from their cohort. Note that temperature is not specified for standard state conditions, but most tables are compiled for this temperature. Question Transcribed Image Text: Which of the following statements is/are TRUE about standard electrode potentials? The calculation of the standard electrode potential of a zinc electrode with the help of the standard hydrogen electrode is illustrated below. 51. These examples are programmatically compiled from various online sources to illustrate current usage of the word 'standard-issue.' at 62-63 (Exhibit 4). Br2(s)+2I(aq)2Br(aq)+I2(l)Ecell=+0.5518V(spontaneous). When the half-cell X is under standard-state conditions, its potential is the standard electrode potential, E X.Since the definition of cell potential requires the half-cells function as cathodes, these potentials are sometimes called standard reduction potentials.. Click the card to flip Ecell is positive for spontaneous reactions. It is defined to be273 K (0 degrees Celsius) and 1 atm pressure (or 105Pa). This approach to measuring electrode potentials is illustrated in Figure 17.6, which depicts a cell comprised of an SHE . Species at the top are more likely to be reduced while species at the bottom are more likely to be oxidized. 61. Br2(s)+2I(aq)2Br(aq)+I2(l)Ecell=+0.5518V(spontaneous)I2(s)+2Br(aq)2I(aq)+Br2(l)Ecell=0.5518V(nonspontaneous) Meador, Derrick. Experts are tested by Chegg as specialists in their subject area. The rural water districts ("RWDs") do not compete against Stilwell for water customers. Comparing Strengths of Oxidants and Reductants For more information view Cell Potentials. Answer of Defendant City of Stilwell, Oklahoma, a Municipal Corporation, and Stilwell Area Development Authority, a Public Trust at 2 (Exhibit 1); Defendants' Answer to CID #12786 at 1 (Exhibit 2); Adair Dep. at 84-89, 133-143, 148-149 (Exhibit 4); Crozier Dep. Adair Dep. There is also ISA, or International Standard Atmosphere, which is101.325 kPa, 15 degrees C and 0 percent humidity, and ICAO Standard Atmosphere, which is atmospheric pressure of 760 mm Hg and a temperature of5 degrees C (288.15 K or 59 degrees F). - Standard Temperature and Pressure, Difference Between Celsius and Centigrade, Standard Molar Entropy Definition in Chemistry, Ph.D., Biomedical Sciences, University of Tennessee at Knoxville, B.A., Physics and Mathematics, Hastings College. PDF AP Chemistry-Electrochemistry - Quia 0.95 g 1.9 g 2.8 g Solved What statement is NOT true about standard | Chegg.com The remaining 5% rely on septic systems. The standard potentials are all measured at 298 K, 1 atm, and with 1 M solutions. B) The electrode potential of the standard hydrogen electrode is exactly zero. The species at the top have a greater likelihood of being reduced while the ones at the bottom have a greater likelihood of being oxidized. The Stilwell UD has for many years operated as the only municipal electric company providing service to the City of Stilwell within its pre-1961 city limits. Langley Dep. at 143 (Exhibit 4). 1999-2023, Rice University. Crozier Dep. at 25-28, 59-60, 62-63, 68, 105 (Exhibit 3). at 32-33, 36, 49-52 (Exhibit 12); Letter from Crozier to Rucker dated April 19,1994 (Exhibit 20).. 43. from suppliers located outside of Oklahoma. 24. are licensed under a, Measurement Uncertainty, Accuracy, and Precision, Mathematical Treatment of Measurement Results, Determining Empirical and Molecular Formulas, Electronic Structure and Periodic Properties of Elements, Electronic Structure of Atoms (Electron Configurations), Periodic Variations in Element Properties, Relating Pressure, Volume, Amount, and Temperature: The Ideal Gas Law, Stoichiometry of Gaseous Substances, Mixtures, and Reactions, Shifting Equilibria: Le Chteliers Principle, The Second and Third Laws of Thermodynamics, Representative Metals, Metalloids, and Nonmetals, Occurrence and Preparation of the Representative Metals, Structure and General Properties of the Metalloids, Structure and General Properties of the Nonmetals, Occurrence, Preparation, and Compounds of Hydrogen, Occurrence, Preparation, and Properties of Carbonates, Occurrence, Preparation, and Properties of Nitrogen, Occurrence, Preparation, and Properties of Phosphorus, Occurrence, Preparation, and Compounds of Oxygen, Occurrence, Preparation, and Properties of Sulfur, Occurrence, Preparation, and Properties of Halogens, Occurrence, Preparation, and Properties of the Noble Gases, Transition Metals and Coordination Chemistry, Occurrence, Preparation, and Properties of Transition Metals and Their Compounds, Coordination Chemistry of Transition Metals, Spectroscopic and Magnetic Properties of Coordination Compounds, Aldehydes, Ketones, Carboxylic Acids, and Esters, Composition of Commercial Acids and Bases, Standard Thermodynamic Properties for Selected Substances, Standard Electrode (Half-Cell) Potentials, Half-Lives for Several Radioactive Isotopes, A cell permitting experimental measurement of the standard electrode potential for the half-reaction, https://openstax.org/books/chemistry-2e/pages/1-introduction, https://openstax.org/books/chemistry-2e/pages/17-3-electrode-and-cell-potentials, Creative Commons Attribution 4.0 International License, Describe and relate the definitions of electrode and cell potentials, Interpret electrode potentials in terms of relative oxidant and reductant strengths, Calculate cell potentials and predict redox spontaneity using standard electrode potentials. at 27 (Exhibit 12); Adair Dep. 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Affidavit of Michael G. Taub (Exhibit 11); see also Zimmerman Dep. cathode. The potential of an electrode is known as the potential of a cell consisting of the electrode concerned acting as a cathode and the standard hydrogen electrode acting as an anode. a. Letter from Cole to Kaufman dated Sept. 13, 1995 (with enclosures) (Exhibit 18); Adair Dep. However, unless specified, assume standard state refers to the higher temperature. 59. Solved Which statement is NOT true about standard electrode - Chegg OpenStax is part of Rice University, which is a 501(c)(3) nonprofit. Adair Dep. This implies that in a spontaneous process, E0cell > 0; which in turn implies that E0cathode > E0anode. This can be done using an activity series. at 5 (Exhibit 6). There is a potential difference between the electrode and the electrolyte called the potential of the electrode. "What Are Some Pros and Cons of the Common Core State Standards?" A 3.2 ampere current is used. 11. Eo cell is positive for spontaneous reactionsB. Water and sewer services are basic needs for the health and welfare of any community. Here, 1 mole of an ideal gas occupies 22.4 L. An older definition used atmospheres for pressure, while modern calculations are for pascals. In contrast, Stilwell offered no rebates and required the developer to dig the trenches and pay for the underground lines. Thus, defendants' market share in the provision of electric service to new customers in the annexed territory is almost 100 percent. Boston, New Jersey: Massachusetts Houghton Miffle Company, 2007. Thus, the standard electrode potential of the cathode and the anode help in predicting the spontaneity of the cell reaction. 53. C) Ecell is positive for spontaneous reactions. 52. However, the standard state isn't usually at the same temperature as STP. Dr. Helmenstine holds a Ph.D. in biomedical sciences and is a science writer, educator, and consultant. What statement is NOT true about standard electrode at 76-77 (Exhibit 6); SOF at 7. at 42-43 (Exhibit 4). What statement is NOT true about standard electrode potentials? Solved 23. What statement is NOT true about standard - Chegg In comparison, to hook up to the City's sewer system, requires only a $150 tap fee, $150 deposit, and minimum bill of $6 per month based upon water usage. By using a galvanic cell in which one side is a SHE, and the other side is half cell of the unknown chemical species, the potential difference from hydrogen can be determined using a voltmeter. Instead, a half-cell potential may only be assessed relative to that of another half-cell. Click 'Join' if it's correct, Best Matched Videos Solved By Our Top Educators. 62. City's Response to Plaintiff's Interrogatories and Request for Production of Documents at 1 (Exhibit 9); Letter from Cole to Read dated October 21, 1997 (Exhibit 10); Adair Dep. What statement is not true about standard electrode - Course Hero What stalement Is NOT true about standard electrode potentials? The standard reduction potential is in a category known as the standard cell potentials or standard electrode potentials. Rucker Dep. See also U.S. Congress, Office of Technology Assessment, Electric Power Wheeling and Dealing: Technological Considerations for Increasing Competition, OTA-E-409 (Washington, DC: U.S. Government Printing Office, May 1989); Cincinnati Gas & Electric Co. v. Federal Power Comm'n, 376 F.2d 506, 507-08 (6th Cir. The electrode in any half-cell with a greater tendency toundergo reduction is positively charged relative to the standardhydrogen electrode and therefore has a positive Eo. I2(s)+2Br(aq)2I(aq)+Br2(l)Ecell=0.5518V(nonspontaneous) What are the Pros and Cons of Charter Schools? Recalling the chapter on thermodynamics, the spontaneities of the forward and reverse reactions of a reversible process show a reciprocal relationship: if a process is spontaneous in one direction, it is non-spontaneous in the opposite direction. What statement is NOT true about standard electrodepotentials?A. The cell potential is found to differ from the standard cell potential by a factor proportional to the natural log of the reaction - (Q) Nonstandard Quotient Match each type of electrochemical cell with the appropriate description For a voltaic cell - DeltaG < 0 For an electrolytic cell - DeltaG > 0 All liquids and gases are pure. a. E^o \text {cell} Eocell is positive for spontaneous reactions b. In support of the accompanying United States' Motion for Summary Judgment, the United States asserts the following material facts as to which there is no genuine issue: 1. at 123, 125 (Exhibit 3). potentials? The Stilwell Area Development Authority is a public trust established under Oklahoma law to provide water and sewer for compensation within and around the City's corporate boundaries. The City of Stilwell is only nine miles from the Arkansas border. To save this word, you'll need to log in. Together they generate more than $340,000 dollars per year in electricity revenues. 21. a) The electrode in any half-cell with a greater tendency to undergo reduction is positively charged relative to the standard hydrogen electrode and therefore has a positive E. 1996). at 124-125 (Exhibit 3); Davidson Dep. Official websites use .gov Rucker Dep. This can be useful for parents and teac.
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